formation of asphaltene deposition during oil production, processing and synthesis is known as a fundamental problem of petroleum reservoir worldwide. asphaltene is a petroleum fraction that can lead to increasing the operating costs in these industries. variations in operational pressure, temperature and fluid composition are generally the significant cause of asphaltene precipitation. in this...

A modified expression for the change in chemical potential of a solvent, in a polymer network, due to isotropic swelling was obtained by substituting a non-Gaussian chain length probability distribution in Flory’s statistical analysis of rubber elasticity. The affine non-Gaussian expression for the free energy change due to elastic deformation was compared to both the traditional Flory and the ...

The occurrence of gelation and the existence of mass-conserving solutions to the continuous coagulation-fragmentation equation are investigated under various assumptions on the coagulation and fragmentation rates, thereby completing the already known results. A non-uniqueness result is also established and a connection to the modified coagulation model of Flory is also made.

The Flory theory for a single polymer chain is derived as the lowest order of a cumulant expansion. In this approach, the full original Flory free energy (including the logarithmic term), is recovered. The prefactors of the elastic and repulsive energy are calculated from the microscopic parameters. The method can be applied to other types of monomer-monomer interactions, and the case of a sing...

A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation)...

Small-angle neutron scattering (SANS) has been employed to study a blend of polystyrene and polybutadiene modified by copolymer additives. SANS data from the one-phase region approaching the phase boundary has been acquired for blends modified by random and diblock copolymers that have equal amounts of styrene and butadiene monomers as well as a random copolymer with an unequal monomer composit...

2014 We develop a Flory theory for the problem of conductivity in a d-dimensional random resistor network. We find that the conductivity exponent t is related to the fractal dimensionality df according to the Alexander-Orbach conjecture t = d 2 + df/2, where consistently with Flory theory df = (d + 2)/2 for percolation and df = 2(d + 2)/5 for lattice animals. The results are in excellent agreem...